Rotational spectroscopy of methyl benzoylformate and methyl mandelate: structure and internal dynamics of a model reactant and product of enantioselective reduction
Author:
Affiliation:
1. Department of Chemistry
2. University of Alberta
3. Edmonton
4. Canada
Abstract
Rotational spectra of a prochiral ester, methyl benzoylformate, and the product of its enantioselective reduction, (R)-(–)-methyl mandelate, were measured, and minimum energy conformers and methyl rotation barriers were determined.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP03114A
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