Rotational spectroscopy of methyl benzoylformate and methyl mandelate: structure and internal dynamics of a model reactant and product of enantioselective reduction-Reference-Cited by-同舟云学术

Rotational spectroscopy of methyl benzoylformate and methyl mandelate: structure and internal dynamics of a model reactant and product of enantioselective reduction

Published:2015 Issue:34 Volume:17 Page:21942-21949
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Schnitzler Elijah G.¹²³⁴,Poopari Mohammad Reza¹²³⁴,Xu Yunjie¹²³⁴,Jäger Wolfgang¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Alberta

3. Edmonton

4. Canada

Abstract

Rotational spectra of a prochiral ester, methyl benzoylformate, and the product of its enantioselective reduction, (R)-(–)-methyl mandelate, were measured, and minimum energy conformers and methyl rotation barriers were determined.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP03114A

Reference65 articles.

1. How nature deals with stereoisomers

2. Nicotinamide adenine dinucleotide, a metabolic regulator of transcription, longevity and disease

3. The first nonenzymic stereospecific intramolecular reduction by an NADH-mimic containing a covalently bound carbonyl moiety

4. Chiral biomimetic NADH models in the benzo[b]-1,6-naphthyridine series. A novel class of stable, reactive and highly enantioselective NADH mimics

5. A novel coenzyme NADH model 1-benzyl-1,4-dihydronicotinamide-mediated reaction: a single intermediate serves two mechanisms

Cited by 6 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Rotational Spectroscopy of the Acetone‐Water Complex: Large Amplitude Motions;ChemPhysChem;2024-08-23

2. Light Absorption by Cinnamaldehyde Constituents of Biomass Burning Organic Aerosol Modeled Using Time-Dependent Density Functional Theory;ACS Earth and Space Chemistry;2023-02-06

3. Two methyl internal rotations of 2-acetyl-4-methylthiophene explored by microwave spectroscopy and quantum chemistry;Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy;2022-11

4. Trends of intramolecular hydrogen bonding in substituted alcohols: a deeper investigation;Physical Chemistry Chemical Physics;2017

5. Contrasting Effects of Water on the Barriers to Decarboxylation of Two Oxalic Acid Monohydrates: A Combined Rotational Spectroscopic and Ab Initio Study;The Journal of Physical Chemistry Letters;2016-03-11