Observations of tetrel bonding between sp3-carbon and THF-Reference-Cited by-同舟云学术

Observations of tetrel bonding between sp3-carbon and THF

Published:2020 Issue:20 Volume:11 Page:5289-5293
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Heywood Victoria L.¹²³⁴,Alford Thomas P. J.¹²³⁴,Roeleveld Julius J.⁵⁶⁷⁸,Lekanne Deprez Siebe J.⁵⁶⁷⁸,Verhoofstad Abraham⁵⁶⁷⁸,van der Vlugt Jarl Ivar⁵⁶⁷⁸⁹^ORCID,Domingos Sérgio R.¹⁰¹¹¹²^ORCID,Schnell Melanie¹⁰¹¹¹²¹³¹⁴^ORCID,Davis Anthony P.¹²³⁴^ORCID,Mooibroek Tiddo J.⁵⁶⁷⁸^ORCID

Affiliation:

1. School of Chemistry

2. University of Bristol

3. Bristol

4. UK

5. van 't Hoff Institute for Molecular Sciences

6. Universiteit van Amsterdam

7. 1098 XH Amsterdam

8. The Netherlands

9. Institute of Chemistry

10. Deutsches Elektronen-Synchrotron (DESY)

11. 22607 Hamburg

12. Germany

13. Institut für Physikalische Chemie

14. Christian-Albrechts-Universität zu Kiel

Abstract

sp³-C⋯THF tetrel bonding was observed in the crystalline state and in the gas phase. Density functional calculations revealed interaction energies up to −11.2 kcal mol⁻¹ and showed that these adducts are held together mainly by electrostatics.

Funder

Deutsche Forschungsgemeinschaft

Stichting voor de Technische Wetenschappen

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC01559H

Reference64 articles.

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