Novel keto–enol tautomerism in 1,3,5-trihydroxybenzene systems-Reference-Cited by-同舟云学术

Novel keto–enol tautomerism in 1,3,5-trihydroxybenzene systems

Published:2020 Issue:85 Volume:56 Page:12985-12988
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ruaysap Makabodee¹²³⁴,Kennedy Stuart R.¹²³⁴,Mayhan Collin M.¹²³⁴,Kelley Steven P.¹²³⁴^ORCID,Kumari Harshita⁵⁶⁷⁴^ORCID,Deakyne Carol A.¹²³⁴,Atwood Jerry L.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Missouri

3. Columbia

4. USA

5. James L. Winkle College of Pharmacy

6. University of Cincinnati

7. Cincinnati

Abstract

We report a new synthesis of the water-soluble compound 1,3,5-trihydroxy-2,4,6-trimethylsulfonic acid (1), which exists in two tautomeric forms (60 : 40::enol%:keto%), and its lanthanide complexes. Relative tautomer stability is influenced by intramolecular H-bonding and competing implicit solvent effects.

Funder

Division of Computer and Network Systems

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC03639K

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4. Controlling Molecular Self-Organization: Formation of Nanometer-Scale Spheres and Tubules

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