Synergy between structural rigidity and cluster defects in a bright near-infrared Cr3+-based phosphor for excellent thermal stability and long afterglow

Author:

Balhara Annu12,Gupta Santosh K.12ORCID,Modak Brindaban23ORCID,Abraham Malini45,Yadav Ashok Kumar6,Annadata Harshini V.6,Das Subrata45ORCID,Rawat Narender Singh27,Sudarshan Kathi12ORCID

Affiliation:

1. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085, India

2. Homi Bhabha National Institute, Anushaktinagar, Mumbai 400094, India

3. Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085, India

4. Materials Science and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram, Kerala 695019, India

5. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

6. Beamline Development & Application Section, Bhabha Atomic Research Centre, Mumbai 400085, India

7. Radiological Physics and Advisory Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085, India

Abstract

This work investigates the important role of structural rigidity and defect related dynamics of a promising garnet phosphor with robust thermal stability for efficient NIR pc-LED devices.

Funder

Department of Atomic Energy, Government of India

Publisher

Royal Society of Chemistry (RSC)

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