Acetate exchange mechanism on a Zr<sub>12</sub> oxo hydroxo cluster: relevance for reshaping Zr–carboxylate coordination adaptable networks-Reference-Cited by-同舟云学术

Acetate exchange mechanism on a Zr₁₂ oxo hydroxo cluster: relevance for reshaping Zr–carboxylate coordination adaptable networks

Published:2023 Issue:30 Volume:14 Page:8152-8163
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Murali Meenu¹,Bijani Christian¹,Daran Jean-Claude¹,Manoury Eric¹,Poli Rinaldo¹²^ORCID

Affiliation:

1. CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, BP 44099, F-31077, Toulouse Cedex 4, France

2. Institut Universitaire de France, 1, rue Descartes, 75231 Paris Cedex 05, France

Abstract

The acetate ligand exchange with free acetic acid in [Zr6O4(OH)4(O2CCH3)12]2, used as a model of crosslink migration in [Zr6O4(OH)4]-based coordination vitrimers, has been thoroughly investigated by dynamic 1H NMR and DFT calculations.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02204H

Reference47 articles.

1. Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers

2. Covalent adaptable networks: smart, reconfigurable and responsive network systems

3. Covalent Adaptable Networks with Tunable Exchange Rates Based on Reversible Thiol–yne Cross‐Linking