Falloff curves and mechanism of thermal decomposition of CF3I in shock waves-Reference-Cited by-同舟云学术

Falloff curves and mechanism of thermal decomposition of CF3I in shock waves

Published:2019 Issue:43 Volume:21 Page:23893-23899
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Cobos C. J.¹²³⁴⁵,Sölter L.⁶⁷⁸⁹,Tellbach E.⁶⁷⁸⁹,Troe J.⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. INIFTA, Facultad de Ciencias Exactas

2. Universidad Nacional de La Plata

3. CONICET

4. La Plata (1900)

5. Argentina

6. Institut für Physikalische Chemie

7. Universität Göttingen

8. D-37077 Göttingen

9. Germany

10. Max-Planck-Institut für Biophysikalische Chemie

Abstract

The falloff curves of the unimolecular dissociation CF₃I (+Ar) → CF₃ + I (+Ar) are modelled by combining quantum-chemical characterization of the potential for the reaction, unimolecular rate theory, and experimental information on collisional energy transfer.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP04771A

Reference56 articles.

1. Experimental and Theoretical Kinetics of High‐Temperature Fluorocarbon Chemistry

2. Thermal Decomposition of CF3 and the Reaction of CF2 + OH → CF2O + H

3. Shock Wave Study of the Thermal Decomposition of CF3 and CF2 Radicals

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5. Falloff Curves of the Reaction CF3 (+M) → CF2 + F (+M);The Journal of Physical Chemistry A;2020-01-24