Modulating the shuttling motion of [2]rotaxanes built of <i>p</i>-xylylenediamine units through permethylation at the benzylic positions of the ring-Reference-Cited by-同舟云学术

Modulating the shuttling motion of [2]rotaxanes built of p-xylylenediamine units through permethylation at the benzylic positions of the ring

Published:2023 Issue:45 Volume:21 Page:9070-9075
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Puigcerver Julio¹^ORCID,Alajarin Mateo¹^ORCID,Martinez-Cuezva Alberto¹^ORCID,Berna Jose¹^ORCID

Affiliation:

1. Departamento de Química Orgánica, Facultad de Química, Regional Campus of International Excellence “Campus Mare Nostrum”, Universidad de Murcia, E-30100 Murcia, Spain

Abstract

A novel permethylated macrocycle allows to modulate rotaxane shuttling rates, revealing untapped strategy for the MIMs’ building.

Funder

Fundación Séneca

Agencia Estatal de Investigación

Ministerio de Ciencia e Innovación

Ministerio de Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB01611K

Reference56 articles.

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2. Catenane and Rotaxane Synthesis from Cucurbit[6]uril‐Mediated Azide‐Alkyne Cycloaddition

3. Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes

4. Controlling catalyst activity, chemoselectivity and stereoselectivity with the mechanical bond

5. Mechanically interlocked molecules in metal–organic frameworks

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