Reaction of the thermo-labile triazenide Na[tBu3SiNNNSiMe3] with CO2: formation of the imido carbonate (tBu3SiO)(Me3SiO)CN-SitBu3and carbamine acid (tBu3SiO)CONH2-Reference-Cited by-同舟云学术

Reaction of the thermo-labile triazenide Na[tBu3SiNNNSiMe3] with CO2: formation of the imido carbonate (tBu3SiO)(Me3SiO)CN-SitBu3and carbamine acid (tBu3SiO)CONH2

Published:2017 Issue:27 Volume:46 Page:8769-8773
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lerner H.-W.¹²³⁴^ORCID,Bolte M.¹²³⁴,Wagner M.¹²³⁴

Affiliation:

1. Institut für Anorganische Chemie

2. Goethe-Universität

3. D-60438 Frankfurt

4. Germany

Abstract

A one-pot synthesis of (tBu₃SiO)(Me₃SiO)CN-SitBu₃and (tBu₃SiO)CONH₂was achieved by the reaction of Na[SitBu₃] with Me₃SiN₃and subsequent CO₂treatment.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00173H

Reference30 articles.

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2. Darstellung und Strukturen der Silyltriazene tBu3Si?N?N?NR?SitBu3 (R = Na, H, Me, SnMe3)

3. Synthese der Amide M[N(SiMetBu2)(SitBu3)] (M = Li, Na) durch N2-Eliminierung aus den Triazeniden M[tBu3SiNNNSiMetBu2] (M = Li, Na) / Synthesis of the Amides M[N(SiMetBu2)(SitBu3)] (M = Li, Na) by N2-Elimination Reaction of the Triazenides M[tBu3SiNNNSiMetBu2] (M= Li, Na)

4. The Sodium Siloxides (tBu3SiONa)4 and (tBu2PhSiONa)4: Synthesis and X-ray Crystal Structure Analysis

5. Silylchalcogenolates MESiRtBu2 (M = Na, Cu, Zn, Fe; E = S, Se, Te; R = tBu, Ph) and Disilyldichalcogenides tBu2RSiE−ESiRtBu2 (E = S, Se, Te; R = tBu, Ph): Synthesis, Properties, and Structures

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