Cu-catalyzed regioselective borylcyanation of 1,3-dienes
Author:
Affiliation:
1. State Key Laboratary of Organometallic Chemistry
2. Center for Excellence in Molecular Synthesis
3. Shanghai Institute of Organic Chemistry
4. University of Chinese Academy of Sciences
5. Chinese Academy of Sciences
Abstract
Catalytic regioselective generation of an allyl–Cu complex through Cu–B(pin) (pin = pinacolato) addition to 1,3-dienes followed by reaction with an electrophilic cyanation reagent to afford multifunctional organoboron compounds is presented.
Funder
National Natural Science Foundation of China
Science and Technology Commission of Shanghai Municipality
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC07032F
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