Aerobic oxidation catalyzed by polyoxometalates associated to an artificial reductase at room temperature and in water

Author:

Naim Ahmad12345ORCID,Chevalier Yoan12345,Bouzidi Younes12345,Gairola Priyanka12345,Mialane Pierre46789,Dolbecq Anne46789,Avenier Frédéric12345ORCID,Mahy Jean-Pierre12345ORCID

Affiliation:

1. LCBB

2. ICMMO

3. Univ Paris-Sud

4. Université Paris Saclay

5. 91405 Orsay

6. UVSQ

7. CNRS

8. UMR 8180

9. Institut Lavoisier de Versailles

Abstract

Four polyoxometalates (POMs) were combined with an artificial reductase based on polyethyleneimine (PEI) and flavin mononucleotide (FMN) which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide (NADH).

Funder

Ministère de l'Enseignement Supérieur et de la Recherche

Centre National de la Recherche Scientifique

Université Paris-Sud

Université Paris-Saclay

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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5. G.-J. Deng , C.-J.Li , R. A.Sheldon and T. H.Chan , Synthetic Chemistry with an Eye on Future Sustainability , 2012

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