11B-NMR shielding effects in theclosoborane series: sensitivity of shifts and their additivity
Author:
Affiliation:
1. Institute of Inorganic Chemistry
2. Academy of Sciences of The Czech Republic
3. The Czech Republic
Abstract
NMR shielding effects for [Xm-closo-BnHn−m]2−anions exhibit a simple linear behaviour in all positions of the borane cluster.
Funder
Grantová Agentura České Republiky
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ02689G
Reference34 articles.
1. Boron-11 NMR spectra of boranes, main-group heteroboranes, and substituted derivatives. Factors influencing chemical shifts of skeletal atoms
2. Antipodal shielding effects in the boron-11, carbon-13, and phosphorus-31 nuclear magnetic resonance spectra of icosahedral carborane derivatives
3. Antipodal and vicinal shift effects in 11B, 13C, and 1H NMR spectra of substituted dicarba-closo-dodecarboranes(12)
4. Directive effects in the electrophilic substitution of deltahedral boranes and heteroboranes. Deuteration and halogenation of 1-thiadecaborane(9) and thiadodecaborane(11)
Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. NMR of carboranes;Comprehensive Inorganic Chemistry III;2023
2. GIAO versus GIPAW: Comparison of Methods To Calculate 11B NMR Shifts of Icosahedral Closo-Heteroboranes toward Boron-Rich Borides;The Journal of Physical Chemistry A;2020-01-30
3. Nuclear Magnetic Shielding of Monoboranes: Calculation and Assessment of 11B NMR Chemical Shifts in Planar BX3 and in Tetrahedral [BX4]− Systems;The Journal of Physical Chemistry A;2017-12-08
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