A mechanistic investigation of anti-elimination in (Z)-1,2-bis(arylseleno)-1-alkenes and their sulfur analogs-Reference-Cited by-同舟云学术

A mechanistic investigation of anti-elimination in (Z)-1,2-bis(arylseleno)-1-alkenes and their sulfur analogs

Published:2015 Issue:21 Volume:13 Page:5964-5971
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Tarao Asami¹²³⁴,Tabuchi Yukako¹²³⁴,Sugimoto Eri¹²³⁴,Ikeda Miki¹²³⁴,Uchimoto Hitomi¹²³⁴,Arimitsu Kenji¹²³⁴,Kimura Hiroyuki⁵⁶⁴,Kawasaki Ikuo¹²³⁴,Kawahata Masatoshi⁷⁸⁹⁴,Yamaguchi Kentaro⁷⁸⁹⁴,Nishide Kiyoharu¹²³⁴

Affiliation:

1. School of Pharmacy and Pharmaceutical Sciences

2. Mukogawa Women's University

3. Nishinomiya

4. Japan

5. Radioisotope Research Center of Kyoto University

6. Sakyo-ku

7. Pharmaceutical Sciences at Kagawa Campus

8. Tokushima Bunri University

9. Sanuki

Abstract

Selenoxide anti-elimination in (Z)-1,2-bis(arylseleninyl)-1-alkenes is induced by the Se⋯O interaction, whereas the sulfur analogs lacks this type of nonbonding interaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00490J

Reference28 articles.

1. Organoselenium Chemistry: Synthesis and Reactions, ed. T. Wirth, Wiley-VCH, 2011, and also see references cited therein

2. Organoselenium Chemistry in Stereoselective Reactions

3. Novel Reactions Using Organoselenium Compounds

4. Functional group manipulation using organoselenium reagents

5. New organoselenium methodology

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