Effect of main and side chain chlorination on the photovoltaic properties of benzodithiophene-alt-benzotriazole polymers

Author:

Bin Haijun1234,Angunawela Indunil5678,Ma Ruijie9101112ORCID,Nallapaneni Asritha138141516,Zhu Chenhui138ORCID,Leenaers Pieter J.1234,Saes Bart W. H.1234,Wienk Martijn M.1234,Yan He9101112ORCID,Ade Harald5678,Janssen René A. J.123417ORCID

Affiliation:

1. Molecular Materials and Nanosystems & Institute for Complex Molecular Systems

2. Eindhoven University of Technology

3. Eindhoven

4. The Netherlands

5. Department of Physics and Organic and Carbon Electronics Laboratories (ORaCEL)

6. North Carolina State University

7. Raleigh

8. USA

9. Department of Chemistry

10. The Hong Kong University of Science and Technology

11. Kowloon

12. Hong Kong

13. Advanced Light Source Lawrence Berkeley National Laboratory Berkeley

14. Department of Polymer Engineering

15. University of Akron

16. Akron

17. Dutch Institute for Fundamental Energy Research

Abstract

Introduction of chlorine in the conjugated side chains significantly improves open-circuit voltage and power conversion efficiency, benefiting from a lower HOMO energy level, well-balanced charge transport and superior nanoscale morphology.

Funder

Office of Naval Research

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Basic Energy Sciences

Ministerie van Onderwijs, Cultuur en Wetenschap

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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