A ring to rule them all: a cyclic ketene acetal comonomer controls the nitroxide-mediated polymerization of methacrylates and confers tunable degradability-Reference-Cited by-同舟云学术

A ring to rule them all: a cyclic ketene acetal comonomer controls the nitroxide-mediated polymerization of methacrylates and confers tunable degradability

Published:2015 Issue:64 Volume:51 Page:12847-12850
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Delplace Vianney¹²³⁴⁵,Guégain Elise¹²³⁴⁵,Harrisson Simon⁶⁷⁸⁹¹⁰,Gigmes Didier¹¹⁷¹²¹³¹⁰,Guillaneuf Yohann¹¹⁷¹²¹³¹⁰,Nicolas Julien¹²³⁴⁵

Affiliation:

1. Institut Galien Paris-Sud

2. Université Paris-Sud

3. UMR CNRS 8612

4. Faculté de Pharmacie

5. F-92296 Châtenay-Malabry cedex

6. Université de Toulouse

7. CNRS

8. Laboratoire des Interactions Moléculaires et Réactivité Chimique et Photochimique UMR 5623

9. F-31062 Toulouse

10. France

11. Aix-Marseille Université

12. Institut de Chimie Radicalaire UMR 7273

13. F-13397 Marseille cedex 20

Abstract

2 Methylene-4-phenyl-1,3-dioxolane (MPDL) was used as a controlling comonomer in NMP with oligo(ethylene glycol) methyl ether methacrylate (MeOEGMA) to prepare well-defined and degradable PEG-based P(MeOEGMA-co-MPDL) copolymers.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04610F

Reference38 articles.

1. Metal-Catalyzed Living Radical Polymerization

2. Living Radical Polymerization by the RAFT Process - A Second Update

3. Nitroxide-mediated polymerization

4. Macromolecular design via reversible addition-fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization

5. Development of a Universal Alkoxyamine for “Living” Free Radical Polymerizations

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