Magnetic coupling between Fe(NO) spin probe ligands through diamagnetic NiII, PdII and PtII tetrathiolate bridges

Author:

Quiroz Manuel1,Lockart Molly M.2,Xue Shan3,Jones Dakota1,Guo Yisong3ORCID,Pierce Brad S.4ORCID,Dunbar Kim R.1,Hall Michael B.1ORCID,Darensbourg Marcetta Y.1ORCID

Affiliation:

1. Department of Chemistry, Texas A &M University, College Station, Texas 77843, USA

2. Department of Chemistry & Biochemistry, Samford University, Birmingham, Alabama 35229, USA

3. Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, USA

4. Department of Chemistry & Biochemistry, University of Alabama, Tuscaloosa, Alabama 35487, USA

Abstract

The nd (n = 3–5) orbital effects on the magnetic coupling within sulfur-bridged, iso-structural, tri-metallic complexes revealed that the heavier congeners significantly enhance superexchange between distal {Fe(NO)}7 radicals: Pt ≫ Pd > Ni.

Funder

Welch Foundation

National Institute of General Medical Sciences

Energy Frontier Research Centers

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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