Rate retardation trends in RAFT – an emerging monomer classification tool?

Author:

Nwoko Tochukwu1ORCID,Nguyen Khoi1ORCID,Saha Nirob K.1,Barner-Kowollik Christopher23ORCID,Konkolewicz Dominik1ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, OH, 45056, USA

2. Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane, Queensland 4000, Australia

3. Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

The RAFT rate retardation effect is used to classify monomers according to their reactivity. The stability of the radical correlates inversely with the extent of retardation allowing a framework for classifying monomer reactivity to be established.

Funder

Division of Chemistry

Australian Research Council

Queensland University of Technology

Publisher

Royal Society of Chemistry (RSC)

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