From imine to amine: an unexpected left turn. Cis-β iron(ii) PNNP′ precatalysts for the asymmetric transfer hydrogenation of acetophenone-Reference-Cited by-同舟云学术

From imine to amine: an unexpected left turn. Cis-β iron(ii) PNNP′ precatalysts for the asymmetric transfer hydrogenation of acetophenone

Published:2017 Issue:9 Volume:8 Page:6531-6541
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Demmans Karl Z.¹²³⁴^ORCID,Seo Chris S. G.¹²³⁴^ORCID,Lough Alan J.¹²³⁴^ORCID,Morris Robert H.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto

4. Canada

Abstract

A slight change in the iron catalyst structure (amine arm with PEt₂ to imine arm with PPh₂) results in a complete reversal of the enantioselectivity toward ketone reduction.

Funder

Canada Foundation for Innovation

Canada Council for the Arts

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02558K

Reference46 articles.

1. Aminoazabenzimidazoles, a Novel Class of Orally Active Antimalarial Agents

2. Biphenyl-Substituted Oxazolidinones as Cholesteryl Ester Transfer Protein Inhibitors: Modifications of the Oxazolidinone Ring Leading to the Discovery of Anacetrapib

3. Discovery of in vitro antitubercular agents through in silico ligand-based approaches

4. Pioneering Perspectives on Asymmetric Hydrogenation†

5. Ruthenium-Catalyzed Selective Hydrogenation for Flavor and Fragrance Applications

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