Tri- and tetra-substituted cyclen based lanthanide(iii) ion complexes as ribonuclease mimics: a study into the effect of log Ka, hydration and hydrophobicity on phosphodiester hydrolysis of the RNA-model 2-hydroxypropyl-4-nitrophenyl phosphate (HPNP)-Reference-Cited by-同舟云学术

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Tri- and tetra-substituted cyclen based lanthanide(iii) ion complexes as ribonuclease mimics: a study into the effect of log Ka, hydration and hydrophobicity on phosphodiester hydrolysis of the RNA-model 2-hydroxypropyl-4-nitrophenyl phosphate (HPNP)

Published:2015 Issue:20 Volume:13 Page:5804-5816
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Fanning Ann-Marie¹²³⁴⁵,Plush Sally. E.⁶⁷⁸⁹¹⁰,Gunnlaugsson Thorfinnur¹²³⁴⁵

Affiliation:

1. School of Chemistry and Trinity Biomedical Sciences Institute

2. University of Dublin

3. Trinity College Dublin

4. Dublin 2

5. Ireland

6. Sansom Institute

7. School of Pharmacy and Medical Sciences

8. University of South Australia

9. Adelaide

10. Australia

Abstract

Lanthanide(iii) complexes of ‘pseudo’ dipeptide ligands and 3'-pyridine ligands have been characterised as metallo-ribonuclease mimics.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02384F

Reference53 articles.

1. Effects of metal ions, including Mg2+ and lanthanides, on the cleavage of ribonucleotides and RNA model compounds.

2. Structure and Nuclease Activity of Simple Dinuclear Metal Complexes: Quantitative Dissection of the Role of Metal Ions

3. Why did Nature select phosphate for its dominant roles in biology?

4. A Proficient Enzyme

5. Catalytic hydrolysis of DNA by metal ions and complexes

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