Structural, magnetic and phase transition properties in S = ½ radical solid solutions of [FxCl1−x-BzPy][Ni(mnt)2] (x = 0.07

Structural, magnetic and phase transition properties in S = ½ radical solid solutions of [F_xCl_1−x-BzPy][Ni(mnt)₂] (x = 0.07–0.87)

Published:2023 Issue:8 Volume:10 Page:2325-2334
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Yao Wan-Wan¹,Ma Bin-Bin¹,Xu Lei¹,Shao Dong-Sheng¹,Qian Yin¹^ORCID,Liu Wen-Long²,Ren Xiao-Ming¹³⁴^ORCID

Affiliation:

1. State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, P. R. China

2. College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

3. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, P. R. China

4. State Key Laboratory of Coordination Chemistry, Nanjing University, 210023, P. R. China

Abstract

The S = ½ spin chain salts [FxCl1−x-BzPy][Ni(mnt)2] (0–1) show a phase transition, and an anomalous change of TC and J/kB with x.

Funder

Priority Academic Program Development of Jiangsu Higher Education Institutions

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D3QI00114H

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