An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature-Reference-Cited by-同舟云学术

An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature

Published:2017 Issue:59 Volume:53 Page:8356-8359
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Pittala Narsimhulu¹²³⁴^ORCID,Thétiot Franck¹²³⁴^ORCID,Charles Catherine¹²³⁴^ORCID,Triki Smail¹²³⁴^ORCID,Boukheddaden Kamel⁵⁶⁷⁴^ORCID,Chastanet Guillaume⁸⁹¹⁰¹¹⁴,Marchivie Mathieu⁸⁹¹⁰¹¹⁴^ORCID

Affiliation:

1. UMR CNRS 6521

2. Univ. Brest (UBO)

3. Brest Cedex 3

4. France

5. UMR-CNRS 8635

6. Univ. Versailles

7. 78035 Versailles

8. CNRS

9. Univ. Bordeaux

10. ICMCB

11. F-33608 Pessac

Abstract

We report a triazole-based trinuclear Fe^II complex as the first example that displays a sharp and complete spin transition. The strong ferro-elastic coupling between the three metal centers was identified as the source of the concerted spin transition.

Funder

Agence Nationale de la Recherche

FP7 Ideas: European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC04112H

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