Dynamical signatures from competing, nonadiabatic fragmentation pathways of S-nitrosothiophenol

Author:

Blackshaw K. Jacob1234,Marracci Marcus5674,Korb Robert T.1234,Quartey Naa-Kwarley1234ORCID,Ajmani Annalise K.1234,Hood David J.1234ORCID,Abelt Christopher J.1234,Ortega Belinda I.5674,Luong Kate5674,Petit Andrew S.5674ORCID,Kidwell Nathanael M.1234ORCID

Affiliation:

1. Department of Chemistry

2. The College of William and Mary

3. Williamsburg

4. USA

5. Department of Chemistry and Biochemistry

6. California State University – Fullerton

7. Fullerton

Abstract

A joint experiment-theory study of the UV photolysis of S-nitrosothiophenol reveals competing photodissociation pathways that produce NO in its spin–orbit ground state and thiophenoxy radical in either its ground or excited electronic state.

Funder

American Chemical Society Petroleum Research Fund

Virginia Space Grant Consortium

California State University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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4. Dimethyl Sulfide and Dimethyl Sulfoxide and Their Oxidation in the Atmosphere

5. J. H. Seinfeld and S. N.Pandis , Atmospheric Chemistry and Physics: From Air Pollution to Climate Change , New York , 3rd edn, 2016

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