Synthesis and extraction studies with a rationally designed diamide ligand selective to actinide(iv) pertinent to the plutonium uranium redox extraction process

Author:

Sharma Shikha1234,Panja Surajit5234,Bhattacharyya Arunasis6234,Dhami Prem S.5234,Gandhi Preetam M.5234,Ghosh Sunil K.1234

Affiliation:

1. Bio-Organic Division

2. Bhabha Atomic Research Centre

3. Mumbai 400085

4. India

5. Fuel Reprocessing Division

6. Radiochemistry Division

Abstract

A new class of rationally designed CHON based conformationally constrained oxa-bridged tricyclo-dicarboxamides rapidly extracted Pu(iv) from PUREX waste solutions with high selectivity and easy stripping as Pu(iii).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference55 articles.

1. B. A. Semenov and N.Oi, Nuclear Fuel Cycles- Adjusting to New Realities, IAEA Bulletin, Vienna, Austria, 1993

2. J. L. Swanson , PUREX Process Flowsheets, in Science and Technology of Tributyl Phosphate, ed. W. W. Schulz, L. L. Burger, J. D. Navratil and K. P. Bender, CRC Press Inc., Boca Raton, 1984, p. 55

3. O. J. Wick , Plutonium Handbook: A Guide to the Technology, American Nuclear Society, La Grangfe Park, Illinois, 1980, vol. 1 and 2

4. NEA , Actinide Separation Chemistry in Nuclear Waste Stream and Material, NEA/NSC/DOC(97)19, Nuclear Energy Agency, OECD, Paris, France, 1997

5. Bicyclic and Acyclic Diamides:  Comparison of Their Aqueous Phase Binding Constants with Nd(III), Am(III), Pu(IV), Np(V), Pu(VI), and U(VI)

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