Crystal, electronic and magnetic structures of a novel series of intergrowth carbometalates R4Co2C3 (R = Y, Gd, Tb)

Author:

Levytskyi Volodymyr1234ORCID,Isnard Olivier5678,Kremer Reinhard K.9104ORCID,Babizhetskyy Volodymyr11121314ORCID,Fontaine Bruno1516171819,Rocquefelte Xavier1516171819ORCID,Halet Jean-François1516171819ORCID,Gumeniuk Roman1234ORCID

Affiliation:

1. Institut für Experimentelle Physik

2. TU Bergakademie Freiberg

3. 09596 Freiberg

4. Germany

5. Institut Néel

6. University Grenoble Alpes and CNRS

7. F-38042 Grenoble cedex 9

8. France

9. Max Planck Institute for Solid State Research

10. D-70569 Stuttgart

11. Department of Inorganic Chemistry

12. Ivan Franko National University of Lviv

13. UA-79005 Lviv

14. Ukraine

15. Univ. Rennes

16. Ecole Nationale Supérieure de Chimie de Rennes

17. CNRS

18. Institut des Sciences Chimiques de Rennes-UMR 6226

19. F-35000 Rennes

Abstract

R4Co2C3 (R = Gd, Tb) carbides are magnetic metals and their crystal structures result from the stacking of alternating RCoC (YCoC-type) and R2C (anti-CdCl2 type) fragments with a 2 : 1 ratio.

Funder

Université Grenoble Alpes

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference41 articles.

1. Recent Progress in Theoretical Prediction, Preparation, and Characterization of Layered Ternary Transition-Metal Carbides

2. Silicon Carbide., Volume 2: Power Devices and Sensors , ed. P. Friedrichs , T. Kimoto , L. Ley and G. Pensl , Wiley-VCH Verlag GmbH & Co. KGaA - Weinheim , 1st edn, 2009 , pp. 520

3. Intermetallic compounds: Their past and promise

4. F. A. Cotton , G.Wilkinson , C. A.Murillo and M.Bochmann , Advanced Inorganic Chemistry , John Wiley and Sons , New York , 6th edn, 1999 , pp. 1376

5. Ternary rare earth and actinoid transition metal carbides viewed as carbometalates

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