Ligand effects in rhodium-catalyzed hydroformylation with bisphosphines: steric or electronic?

Author:

Jiao Yunzhe12345ORCID,Torne Marta Serrano1234,Gracia Jose5678,Niemantsverdriet J. W. (Hans)56789,van Leeuwen Piet W. N. M.1234ORCID

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ)

2. The Barcelona Institute of Science and Technology

3. 43007 Tarragona

4. Spain

5. SynCat@Beijing

6. Synfuels China Technology Co. Ltd

7. Beijing

8. P.R. China

9. Syngaschem BV

Abstract

Do wide bite angles lead to high linear regioselectivity in hydroformylation, or is an electronic effect operative?

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference41 articles.

1. C. Claver and P. W. N. M.van Leeuwen, Rhodium Catalyzed Hydroformylation, Kluwer Academic Publishers, Dordrecht, 2000

2. A. Behr and P.Neubert, Applied Homogeneous Catalysis, John Wiley & Sons, Weinheim, 2012

3. B. Cornils and W. A.Herrmann, Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Three Volumes, Wiley, Weinheim, 2002, vol. 3

4. Ligands for Practical Rhodium-Catalyzed Asymmetric Hydroformylation

5. Applied Hydroformylation

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