An iron phosphate hydroxide hydrate electrocatalyst: synergistic effects of Fe2+ and Fe3+ for enhanced hydrogen evolution reaction stability

Author:

Reddy Jeygeerthika1,Raman Vivekanandan2ORCID,Viswanathan K. K.3,Prabakar Kandasamy1ORCID

Affiliation:

1. Department of Electrical and Electronics Engineering, Pusan National University, 2 Busandaehak-ro 63beon-gil, Geumjeong-gu, Busan 46241, Republic of Korea

2. School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, South Korea

3. Department of Mathematical Modeling, Faculty of Mathematics, Samarkand State University, Samarkand, 140104, Uzbekistan

Abstract

Synthesized via unique electrodeposition, Fe3(PO4)(OH)6·3H2O HER catalyst, with varied ratios, boasts enriched Fe3+/Fe2+ sites. In 1 M KOH, it excels with a low 130 mV overpotential, 87 mV dec−1 Tafel value, and 80 hour durability at 100 mA cm−2.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

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