Facile photo-flow synthesis of branched poly(butyl acrylate)s

Author:

Eckardt O.12345,Wenn B.678910,Biehl P.12345,Junkers T.678910ORCID,Schacher F. H.12345ORCID

Affiliation:

1. Institute of Organic Chemistry and Macromolecular Chemistry (IOMC)

2. Friedrich-Schiller-University Jena

3. D-07443 Jena

4. Germany

5. Jena Center for Soft Matter (JCSM)

6. Polymer Reaction Design Group (PRD)

7. Institute of Materials Research (IMO)

8. Hasselt University

9. BE-3500 Hasselt

10. Belgium

Abstract

We present the synthesis of branched poly(butyl acrylate)s using photo-induced free radical polymerization of (n/t)-butyl acrylate in the presence of tri(propylene glycol) diacrylate (TPGDA) as a crosslinker and varying amounts of dodecanethiol (DDT) as a chain transfer agent to prevent macroscopic gelation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

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