Complications in complexation kinetics for lanthanides with DTPA using dye probe molecules in aqueous solution-Reference-Cited by-同舟云学术

Complications in complexation kinetics for lanthanides with DTPA using dye probe molecules in aqueous solution

Published:2017 Issue:42 Volume:7 Page:26507-26512
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Larsson K.¹²³⁴^ORCID,Cullen T. D.¹²³⁴,Mezyk S. P.¹²³⁴^ORCID,McDowell R. G.⁵⁶⁷⁴^ORCID,Martin L. R.⁵⁶⁷⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. California State University Long Beach

3. Long Beach

4. USA

5. Aqueous Separations and Radiochemistry Department

6. Idaho National Laboratory

7. Idaho Falls

Abstract

Dye probe molecules were used to investigate lanthanide complexation and verify the viability of the ligand displacement methodology for measuring DTPA complexation rate constants. Results showed that dye probes underestimate the rate constants.

Funder

Nuclear Energy University Programs

Office of Nuclear Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA04755J

Reference33 articles.

1. Design and Synthesis of Macrocyclic Ligands and Their Complexes of Lanthanides and Actinides

2. Equilibria and dissociation kinetics of lanthanide complexes of diaza crown ether carboxylic acids

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4. Solid-State and Solution-State Coordination Chemistry of Lanthanide(III) Complexes with α-Hydroxyisobutyric Acid

5. Preferential extraction of lanthanides over trivalent actinides by monoacidic organophosphates from carboxylic acids and from mixtures of carboxylic and aminopolyacetic acids

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