Formation and reactions of active five-membered phosphane/borane frustrated Lewis pair ring systems
Author:
Affiliation:
1. Organisch-Chemisches Institut
2. Westfälische Wilhelms-Universität Münster
3. Münster
4. Germany
5. Institut für Physikalische Chemie and Graduate School of Chemistry
6. 48149 Münster
7. Institute of Physics in Sao Carlos
Abstract
The five-membered P/B FLP ring systems featuring very bulky Tipp or Mes* aryl groups at phosphorus undergo addition reactions with organic π-reagents.
Funder
H2020 European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00672E
Reference33 articles.
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3. Hydroboration. 42. Cyclic hydroboration of representative acyclic .alpha.,.omega.-dienes with monochloroborane etherate
4. Hydroboration—a powerful synthetic tool
5. Organoboranes for synthesis - substitution with retention
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