Highly planar diarylamine-fused porphyrins and their remarkably stable radical cations-Reference-Cited by-同舟云学术

Highly planar diarylamine-fused porphyrins and their remarkably stable radical cations

Published:2017 Issue:1 Volume:8 Page:189-199
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Fukui Norihito¹²³⁴⁵,Cha Wonhee⁶⁷⁸⁹,Shimizu Daiki¹²³⁴⁵,Oh Juwon⁶⁷⁸⁹,Furukawa Ko¹⁰¹¹¹²⁵,Yorimitsu Hideki¹²³⁴⁵,Kim Dongho⁶⁷⁸⁹,Osuka Atsuhiro¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Kyoto University

4. Kyoto 606-8502

5. Japan

6. Spectroscopy Laboratory of Functional π-Electronic Systems and Department of Chemistry

7. Yonsei University

8. Seoul 120-749

9. Korea

10. Center for Instrumental Analysis

11. Niigata University

12. Niigata 950-2181

Abstract

Oxidative fusion of a meso-phenoxazino Ni(ii) porphyrin at high temperature gave a doubly phenoxazine-fused porphyrin as a highly planar diarylamine-fused porphyrin. One-electron oxidation of the corresponding β,β-dichlorinated compound gave a remarkably stable radical cation.

Funder

Japan Society for the Promotion of Science

Asahi Glass Foundation

Ministry of Education, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC02721K

Reference78 articles.

1. Photoinduced electron transfer in supramolecular systems for artificial photosynthesis