Reactivity of Schiff base-[C,N,S] pincer palladacycles: hydrolysis renders singular trinuclear, tetranuclear, and heteropentanuclear Pd3W2 coordinated complexes

Author:

Reigosa Francisco1ORCID,Polo Paula M.1,Pereira M. Teresa1ORCID,Vila José M.1ORCID

Affiliation:

1. Departamento de Química Inorgánica, Universidad de Santiago de Compostela, E-15782 Santiago de Compostela, Spain

Abstract

Schiff base palladacycles undergo singular transformations to render six- and eight-membered Pd3N3 and Pd4N4 ring complexes, and a penta-nuclear Pd3W2trans-configured heterometallic linear compound.

Funder

Ministerio de Ciencia e Innovación

Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia

Publisher

Royal Society of Chemistry (RSC)

Reference45 articles.

1. M. T.Pereira and J. M.Vila , The P-C Building Block of Palladacycles: A Cornerstone for Stoichiometric C-C and C-X Bond Assemblage , in Palladacycles. Synthesis, Characterization and Applications , ed. J. Dupont and M. Pfeffer , Wiley-VCH , 2008 , pp. 87–108

2. J. M.Vila , M. T.Pereira , F.Lucio-Martínez and F.Reigosa , Palladacycles as Efficient Precatalysts for Suzuki-Miyaura Cross-Coupling Reactions , Palladacycles. Catalysis and Beyond , 2019 , pp. 1–20

3. Formation of Covalent Bonds from Platinum or Palladium to Carbon by Direct Substitution

4. Intramolecular five-membered ring compounds and their applications

5. J.Tsuji , Palladium Reagents and Catalysts , 2004 , vol. 9 , 10.1002/0470021209

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