Tetrathiafulvalene-based covalent organic frameworks as high-voltage organic cathodes for lithium batteries

Author:

Valente Gonçalo1,Dantas Raquel1ORCID,Ferreira Pedro1,Grieco Rebecca2,Patil Nagaraj2ORCID,Guillem-Navajas Ana3ORCID,Rodríguez-San Miguel David34ORCID,Zamora Félix35ORCID,Guntermann Roman6ORCID,Bein Thomas6,Rocha João1ORCID,Braga M. Helena78ORCID,Strutyński Karol1ORCID,Melle-Franco Manuel1ORCID,Marcilla Rebeca2ORCID,Souto Manuel19ORCID

Affiliation:

1. Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Aveiro, 3810-393, Portugal

2. Electrochemical Processes Unit, IMDEA Energy Institute, Avda. Ramón de La Sagra 3, 28935 Móstoles, Spain

3. Departamento de Química Inorgánica, Universidad Autónoma de Madrid, Madrid, 28049, Spain

4. Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, 28049 Madrid, Spain

5. Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, 28049 Madrid, Spain

6. Department of Chemistry and Center for NanoScience (CeNS), Ludwig-Maximilians-Universität München, Butenandtstraße 5-13 (E), 81377 Munich, Germany

7. Engineering Physics Department, Engineering Faculty, University of Porto, 4200-465 Porto, Portugal

8. MatER – Materials for Energy Research Laboratory, Engineering Faculty, University of Porto, Portugal

9. CiQUS, Centro Singular de Investigación en Química Bioloxica e Materiais Moleculares, Departamento de Química-Física, Universidade de Santiago de Compostela, 15782, Santiago de Compostela, Spain

Abstract

We report a series of 2D tetrathiafulvalene (TTF)-based COFs incorporating different organic linkers between the electroactive moieties that were investigated as p-type organic cathode materials for lithium-organic batteries.

Funder

HORIZON EUROPE Framework Programme

Centro de Investigação em Materiais Cerâmicos e Compósitos

Universidade de Aveiro

Deutsche Forschungsgemeinschaft

Fundação para a Ciência e a Tecnologia

H2020 Marie Skłodowska-Curie Actions

HORIZON EUROPE European Innovation Council

Publisher

Royal Society of Chemistry (RSC)

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