Expanding the reaction space of aldolases using hydroxypyruvate as a nucleophilic substrate-Reference-Cited by-同舟云学术

Expanding the reaction space of aldolases using hydroxypyruvate as a nucleophilic substrate

Published:2017 Issue:2 Volume:19 Page:519-526
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

de Berardinis Véronique¹²³⁴⁵,Guérard-Hélaine Christine⁶⁷⁸⁹¹⁰,Darii Ekaterina¹²³⁴⁵,Bastard Karine¹²³⁴⁵,Hélaine Virgil⁶⁷⁸⁹¹⁰,Mariage Aline¹²³⁴⁵,Petit Jean-Louis¹²³⁴⁵,Poupard Nicolas⁶⁷⁸⁹¹⁰,Sánchez-Moreno Israel⁶⁷⁸⁹¹⁰,Stam Mark¹²³⁴⁵,Gefflaut Thierry⁶⁷⁸⁹¹⁰,Salanoubat Marcel¹²³⁴⁵,Lemaire Marielle⁶⁷⁸⁹¹⁰

Affiliation:

1. CEA

2. DRF

3. IG

4. Genoscope

5. UMR 8030

6. Clermont Université

7. Université Blaise Pascal

8. F-63000 Clermont-Ferrand

9. France

10. CNRS

Abstract

Hydroxypyruvate was shown to be a nucleophile for class II pyruvate aldolases isolated from biodiversity, allowing unprecedented stereoselective cross-aldol reactions.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/GC/C6GC02652D

Reference56 articles.

1. Total Syntheses of Carbohydrates: Organocatalyzed Aldol Additions of Dihydroxyacetone

2. Organocatalytic synthesis of carbohydrates

3. Current Trends in Asymmetric Synthesis with Aldolases

4. Recent progress in stereoselective synthesis with aldolases

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