Supramolecular ultrafast energy and electron transfer in a directly linked BODIPY–oxoporphyrinogen dyad upon fluoride ion binding

Author:

Chahal Mandeep K.1234ORCID,Liyanage Anuradha5678,Gobeze Habtom B.5678,Payne Daniel T.1234ORCID,Ariga Katsuhiko1234ORCID,Hill Jonathan P.1234ORCID,D’Souza Francis5678ORCID

Affiliation:

1. International Center for Materials Nanoarchitectonics (WPI-MANA)

2. National Institute of Materials Science (NIMS)

3. Ibaraki

4. Japan

5. Department of Chemistry

6. University of North Texas

7. Denton

8. USA

Abstract

Photosynthetic mimicry of sequential ultrafast energy transfer followed by electron transfer upon fluoride binding to the oxoporphyrinogen cavity in a BODIPY–oxoporphyrinogen dyad is demonstrated.

Funder

Core Research for Evolutional Science and Technology

National Science Foundation

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference36 articles.

1. The Photosynthetic Reaction Center , ed. J. Deisenhofer and J. R. Norris , Academic Press , New York , 1993

2. W. Leibl and P.Mathis , Electron Transfer in Photosynthesis. Series on Photoconversion of Solar Energy , 2004 , vol. 2, p. 117

3. Solar Fuels via Artificial Photosynthesis

4. Self-Assembly Strategies for Integrating Light Harvesting and Charge Separation in Artificial Photosynthetic Systems

5. Covalent and Noncovalent Phthalocyanine−Carbon Nanostructure Systems: Synthesis, Photoinduced Electron Transfer, and Application to Molecular Photovoltaics

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