Temperature dependence of photophysical properties of a dinuclear C^N-cyclometalated Pt(ii) complex with an intimate Pt–Pt contact. Zero-field splitting and sub-state decay rates of the lowest triplet

Author:

Deaton Joseph C.1234,Chakraborty Arnab1234,Czerwieniec Rafal5678,Yersin Hartmut5678ORCID,Castellano Felix N.1234ORCID

Affiliation:

1. Department of Chemistry

2. North Carolina State University

3. Raleigh

4. USA

5. Institut für Physikalische Chemie

6. Universität Regensburg

7. D-93040 Regensburg

8. Germany

Abstract

A dinuclear Pt(ii) complexes exhibits an unusually large zero field splitting in its metal–metal-to-ligand charge transfer triplet excited state.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference115 articles.

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2. J. A. G. Williams in Topics in Organometallic Chemistry , ed. H. Bozec and V. Guerchais , Springer , New York , 2009

3. Cyclometalated Platinum Complexes with Luminescent Quantum Yields Approaching 100%

4. Single-Doped White Organic Light-Emitting Device with an External Quantum Efficiency Over 20%

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