Electrical conductivity in two mixed-valence liquids-Reference-Cited by-同舟云学术

Electrical conductivity in two mixed-valence liquids

Published:2015 Issue:21 Volume:17 Page:14107-14114
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Yao Wenzhi¹²³⁴,Kelley Steven P.¹²³⁴,Rogers Robin D.¹²³⁴,Vaid Thomas P.¹²³⁴

Affiliation:

1. Department of Chemistry

2. The University of Alabama

3. Tuscaloosa

4. USA

Abstract

Two mixed-valence room-temperature liquids are reported: BuFc–[BuFc⁺][NTf₂⁻] (BuFc = n-butylferrocene) and TEMPO–[TEMPO⁺][NTf₂⁻]. Both are conductors of DC electrical current, and their conductivity is modeled based on the electron-transfer self-exchange rate constants of their constituent redox-active species.

Funder

Nuclear Energy University Programs

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP01172H

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