Structure and excited-state dynamics of dimeric copper(i) photosensitizers investigated by time-resolved X-ray and optical transient absorption spectroscopy-Reference-Cited by-同舟云学术

Structure and excited-state dynamics of dimeric copper(i) photosensitizers investigated by time-resolved X-ray and optical transient absorption spectroscopy

Published:2021 Issue:5 Volume:23 Page:3656-3667
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Velasco Lucía¹²³⁴,Llanos Leonel⁵⁶⁷⁸,Levín Pedro⁵⁶⁷⁸^ORCID,Vega Andrés⁹¹⁰¹¹¹²⁸^ORCID,Yu Jin¹³¹⁴¹⁵¹⁶¹⁷,Zhang Xiaoyi¹³¹⁴¹⁵¹⁶¹⁷,Lemus Luis⁵⁶⁷⁸^ORCID,Aravena Daniel⁵⁶⁷⁸^ORCID,Moonshiram Dooshaye¹²³⁴^ORCID

Affiliation:

1. Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA Nanociencia)

2. Calle Faraday, 9

3. 28049 Madrid

4. Spain

5. Departamento de Química de los Materiales

6. Universidad de Santiago de Chile

7. Santiago

8. Chile

9. Facultad de Ciencias Exactas

10. Departamento de Ciencias Químicas

11. Universidad Andrés Bello

12. Viña de Mar

13. X-ray Science Division

14. Argonne National Laboratory

15. 9700 S. Cass Avenue

16. Lemont IL

17. USA

Abstract

Three homoleptic Cu(i) dimeric photosensitizers are studied through ultrafast X-ray and optical absorption spectroscopy. The complexes show distinct excited state lifetimes, due to the solvent type and spacers' flexibilities between the Cu centres.

Funder

Horizon 2020 Framework Programme

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP06080A

Reference97 articles.

1. The Artificial Leaf

2. Photocatalytic hydrogen production

3. Molecular artificial photosynthesis

4. Nickel–Thiolate Complex Catalyst Assembled in One Step in Water for Solar H2 Production

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