Dual roles of ynoates: desymmetrization of dicarboxylic acids using trialkylamines as alkyl equivalents-Reference-Cited by-同舟云学术

Dual roles of ynoates: desymmetrization of dicarboxylic acids using trialkylamines as alkyl equivalents

Published:2018 Issue:20 Volume:5 Page:2955-2959
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Xu Xianjun¹²³⁴,Huang Liliang¹²³⁴,Yin Xiaoying¹²³⁴,Van der Eycken Erik V.⁵⁶⁷⁸⁹^ORCID,Feng Huangdi¹²³⁴^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Shanghai University of Engineering Science

3. Shanghai

4. China

5. Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC)

6. Department of Chemistry

7. KU Leuven

8. Leuven 3001

9. Belgium

Abstract

A novel method has been developed for the desymmetrization of aromatic dicarboxylic acids by employing an esterification reaction/conjugate addition of a carboxyl group to ynoates, which can trigger a coupling reaction.

Funder

Natural Science Foundation of Shanghai

China Postdoctoral Science Foundation

Shanghai Key Laboratory of Chemical Biology

Shanghai University of Engineering and Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00919H

Reference49 articles.

1. Recent Developments in Amide Synthesis Using Nonactivated Starting Materials

2. Nonclassical Routes for Amide Bond Formation

3. Catalytic amide formation from non-activated carboxylic acids and amines

4. The Mitsunobu reaction in the 21st century

5. Ester coupling reactions – an enduring challenge in the chemical synthesis of bioactive natural products

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