Dual roles of ynoates: desymmetrization of dicarboxylic acids using trialkylamines as alkyl equivalents

Author:

Xu Xianjun1234,Huang Liliang1234,Yin Xiaoying1234,Van der Eycken Erik V.56789ORCID,Feng Huangdi1234ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Shanghai University of Engineering Science

3. Shanghai

4. China

5. Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC)

6. Department of Chemistry

7. KU Leuven

8. Leuven 3001

9. Belgium

Abstract

A novel method has been developed for the desymmetrization of aromatic dicarboxylic acids by employing an esterification reaction/conjugate addition of a carboxyl group to ynoates, which can trigger a coupling reaction.

Funder

Natural Science Foundation of Shanghai

China Postdoctoral Science Foundation

Shanghai Key Laboratory of Chemical Biology

Shanghai University of Engineering and Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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