Reactivity of cyclopentadienyl transition metal(ii) complexes with borate ligands: structural characterization of the toluene-activated molybdenum complex [Cp*Mo(CO)2(η3-CH2C6H5)]-Reference-Cited by-同舟云学术

Reactivity of cyclopentadienyl transition metal(ii) complexes with borate ligands: structural characterization of the toluene-activated molybdenum complex [Cp*Mo(CO)2(η3-CH2C6H5)]

Published:2016 Issue:41 Volume:45 Page:16317-16324
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ramalakshmi Rongala¹²³⁴⁵,Maheswari K.¹²³⁴,Sharmila Dudekula¹²³⁴,Paul Anamika¹²³⁴,Roisnel Thierry⁵⁶⁷⁸,Halet Jean-François⁵⁶⁷⁸,Ghosh Sundargopal¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Madras

3. Chennai 600 036

4. India

5. Institut des Sciences Chimiques de Rennes

6. UMR 6226 CNRS-Université de

7. F-35042 Rennes Cedex

8. France

Abstract

Unprecedented formation of a toluene activated complex, [Cp*Mo(CO)₂(CH₂C₆H₅)], in an η³-fashion was elucidated by the reaction of [Cp*Mo(CO)₃Cl] with [NaBt₂].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02641A

Reference101 articles.

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5. A. E. Shilov and G. B.Shulpin, Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, Kluwer, Boston, 2000, vol. 21

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