Cubane-like tetranuclear Cu(ii) complexes bearing a Cu4O4 core: crystal structure, magnetic properties, DFT calculations and phenoxazinone synthase like activity

Author:

Sagar Shipra1234,Sengupta Swaraj12341,Mota Antonio J.56789,Chattopadhyay Shyamal K.110114ORCID,Espinosa Ferao Arturo1213149,Riviere Eric1516171819,Lewis William20212223ORCID,Naskar Subhendu1234ORCID

Affiliation:

1. Department of Chemistry

2. Birla Institute of Technology

3. Ranchi-835215

4. India

5. Department of Inorganic Chemistry

6. Faculty of Sciences

7. University of Granada

8. 18002 Granada

9. Spain

10. Indian Institute of Engineering Science and Technology-Shibpur

11. Howrah-711103

12. Department of Organic Chemistry

13. University of Murcia

14. 30100 Murcia

15. Equipe Chimie Inorganique

16. Institut de Chimie Moléculaire et des Matériaux d'Orsay

17. Université Paris Sud

18. 91400 Orsay

19. France

20. School of Chemistry

21. University of Nottingham

22. Nottingham NG7 2RD

23. UK

Abstract

Two tetranuclear copper complexes with a Cu4O4 cubane core exhibiting phenoxazinone synthase like activity are reported.

Funder

Council for Scientific and Industrial Research

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference75 articles.

1. T. Mallah and A.Marvilliers, in Magnetism: Molecules to Materials II, Wiley-VCH Verlag GmbH & Co., Weinheim, Germany, 2001, pp. 189–226

2. Synthesis of 3d Metallic Single-Molecule Magnets

3. Structural and Functional Aspects of Metal Sites in Biology

4. Copper(II) Complexes of Aminocarbohydrateβ-Ketoenaminic Ligands: Efficient Catalysts in Catechol Oxidation

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