Unveiling the genesis of the high catalytic activity in nickel phthalocyanine for electrochemical ammonia synthesis-Reference-Cited by-同舟云学术

Unveiling the genesis of the high catalytic activity in nickel phthalocyanine for electrochemical ammonia synthesis

Published:2021 Issue:25 Volume:9 Page:14477-14484
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Murmu Shyamal¹²³⁴⁵,Paul Sourav¹²³⁴⁵,Kapse Samadhan⁶⁷⁸⁹,Thapa Ranjit⁶⁷⁸⁹,Chattopadhyay Santanu¹⁰¹¹¹²⁹^ORCID,N. Abharana¹³¹⁴¹⁵⁹,Jha Shambhu N.¹³¹⁴¹⁵⁹,Bhattacharyya Dibyendu¹³¹⁴¹⁵⁹,Ghorai Uttam Kumar¹²³⁴⁵^ORCID

Affiliation:

1. Department of Industrial Chemistry & Applied Chemistry

2. Swami Vivekananda Research Centre

3. Ramakrishna Mission Vidyamandira

4. Belur Math

5. Howrah

6. Department of Physics

7. SRM University – AP

8. Amaravati

9. India

10. Rubber Technology Centre

11. Indian Institute of Technology

12. Kharagpur

13. Atomic & Molecular Physics Division

14. Bhabha Atomic Research Centre

15. Mumbai

Abstract

DFT is applied to identify the active sites of NiPc for NRR and its catalytic origination. Accordingly, NiPc nanorods, synthesized by solvothermal method, exhibit NH₃ yield rate of 85 μg h⁻¹ mg_cat⁻¹ and FE of 25% at −0.3 V vs. RHE.

Funder

Department of Science and Technology, Government of West Bengal

Board of Research in Nuclear Sciences

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology, India

Department of Biotechnology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/TA/D1TA00766A