Transition metal incorporation: electrochemical, structure, and chemical composition effects on nickel oxyhydroxide oxygen-evolution electrocatalysts-Reference-Cited by-同舟云学术

Transition metal incorporation: electrochemical, structure, and chemical composition effects on nickel oxyhydroxide oxygen-evolution electrocatalysts

Published:2024 Issue:5 Volume:17 Page:2028-2045
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Marquez Raul A.¹^ORCID,Kalokowski Emma¹^ORCID,Espinosa Michael¹^ORCID,Bender Jay T.²^ORCID,Son Yoon Jun²,Kawashima Kenta¹^ORCID,Chukwuneke Chikaodili E.¹^ORCID,Smith Lettie A.¹^ORCID,Celio Hugo³,Dolocan Andrei³,Zhan Xun³,Miller Nathaniel⁴,Milliron Delia J.¹²^ORCID,Resasco Joaquin²^ORCID,Mullins C. Buddie¹²³⁵⁶^ORCID

Affiliation:

1. Department of Chemistry, The University of Texas at Austin, Austin, Texas 78712, USA

2. McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712, USA

3. Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, USA

4. Department of Geosciences, The University of Texas at Austin, Austin, Texas 78712, USA

5. Center for Electrochemistry, The University of Texas at Austin, Austin, Texas 78712, USA

6. H2@UT, The University of Texas at Austin, Austin, Texas 78712, USA

Abstract

Trace metal cations dissolved in alkaline electrolytes incorporate into nickel hydroxide/oxyhydroxide through in situ cation exchange, creating an interstratified structure near the surface of the material that impacts the electrochemical performance.

Funder

Welch Foundation

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/EE/D3EE03617K

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