Ligand–metal cooperativity in quinonoid based nickel(<scp>ii</scp>) and cobalt(<scp>ii</scp>) complexes for catalytic hydrosilylative reduction of nitriles to amines: electron transfer and mechanistic insight-Reference-Cited by-同舟云学术

Ligand–metal cooperativity in quinonoid based nickel(ii) and cobalt(ii) complexes for catalytic hydrosilylative reduction of nitriles to amines: electron transfer and mechanistic insight

Published:2023 Issue:15 Volume:52 Page:4964-4972
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Paramanik Krishnendu¹,Bandopadhyay Nilaj¹,Sarkar Gayetri¹,Chatterjee Souvik¹,Roy Suvojit¹,Panda Subhra Jyoti²,Purohit Chandra Shekhar²^ORCID,Biswas Bhaskar¹^ORCID,Das Hari Sankar¹^ORCID

Affiliation:

1. Department of Chemistry, University of North Bengal, Darjeeling 734013, India

2. Department of Chemical Sciences, National Institute of Science Education and Research, Bhubaneswar, Orissa-751005, India

Abstract

Non-innocent quinonoid ligand based square-planar Ni(ii) and Co(ii) complexes showing excellent catalytic activity towards hydrosilylative reduction of nitrile to corresponding primary amine using an inexpensive hydrosilane PMHS.

Funder

Council of Scientific and Industrial Research, India

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00090G

Reference70 articles.

1. Industrial processes for manufacturing amines

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