Tracking nitrite's deviation from Stokes–Einstein predictions with pulsed field gradient <sup>15</sup>N NMR spectroscopy-Reference-Cited by-同舟云学术

Tracking nitrite's deviation from Stokes–Einstein predictions with pulsed field gradient ¹⁵N NMR spectroscopy

Published:2023 Issue:97 Volume:59 Page:14407-14410
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Graham Trent R.¹^ORCID,Wei Yihui²,Walter Eric D.¹^ORCID,Nienhuis Emily T.¹^ORCID,Chun Jaehun¹^ORCID,Schenter Gregory K.¹^ORCID,Rosso Kevin M.¹^ORCID,Pearce Carolyn I.¹³^ORCID,Clark Aurora E.²^ORCID

Affiliation:

1. Pacific Northwest National Laboratory, Richland, Washington 99354, USA

2. Department of Chemistry, University of Utah, Salt Lake City, Utah, 84112, USA

3. Department of Crop and Soil Sciences, Washington State University, Pullman, Washington 99164, USA

Abstract

The diffusivities of nitrite in concentrated sodium nitrite and simulant radioactive waste observed with 15N PFGSTE-NMR spectroscopy exceeded predictions based on the Stokes–Einstein relationship.

Funder

U.S. Department of Energy

Battelle

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC04168A

Reference37 articles.

1. A. R.Felmy , J. R.Rustad , M. J.Mason and R. D. L.Bretonne , A chemical model for the major electrolyte components of the Hanford waste tanks. The binary electrolytes in the system: Na-NO 3 -NO 2 -SO 4 -CO 3 -F-PO 4 -OH-AI(OH) 4 -H 2 O , United States, 1994

2. R. L.Russell , H. D.Smith , D. E.Rinehart and R. A.Peterson , Development and Characterization of Gibbsite Component Simulant, United States, 2009

3. Ion–ion interactions enhance aluminum solubility in alkaline suspensions of nano-gibbsite (α-Al(OH)3) with sodium nitrite/nitrate

4. D. L.Herting , Effect of Phosphate, Fluoride, and Nitrate on Gibbsite Dissolution Rate and Solubility, United States, 2014

5. A Review of Sodium Nitrite Solubility in Water and Physical Properties of the Saturated Solutions