Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of α-fluorophosphonates-Reference-Cited by-同舟云学术

Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of α-fluorophosphonates

Published:2014 Issue:51 Volume:50 Page:6751-6753
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Huang Ying¹²³⁴,Zhang Qing-Song⁵⁶⁷⁸,Fang Ping⁵⁶⁷⁸,Chen Tie-Gen⁵⁶⁷⁸,Zhu Jun¹²³⁴,Hou Xue-Long⁵⁶⁷⁸

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry

2. College of Chemistry and Chemical Engineering

3. Xiamen University

4. Xiamen 361005, China

5. State Key Laboratory of Organometallic Chemistry

6. Shanghai Institute of Organic Chemistry

7. Chinese Academy of Sciences

8. Shanghai 200032, China

Abstract

α-Fluorophosphonates with two chiral centers have been synthesised in high diastereo- and enatioselectivites via Pd-catalyzed AAA of 2-fluoro-2-(diethoxyphosphoryl)acetate with monosubstituted allylic substrates. Their transformations were also demonstrated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC02158D

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