Leak-out spectroscopy as alternative method to rare-gas tagging for the Renner–Teller perturbed HCCH+ and DCCD+ ions

Author:

Steenbakkers Kim1,van Boxtel Tom1,Groenenboom Gerrit C.2ORCID,Asvany Oskar3ORCID,Redlich Britta1,Schlemmer Stephan3ORCID,Brünken Sandra1ORCID

Affiliation:

1. Radboud University, FELIX Laboratory, Institute for Molecules and Materials, Nijmegen, The Netherlands

2. Radboud University, Institute for Molecules and Materials, Nijmegen, The Netherlands

3. I. Physikalisches Institut, Universität zu Köln, Köln, Germany

Abstract

Vibronic coupling effects in the low-lying bending modes of the open-shell linear ions HCCH+ and DCCD+ have been investigated using cryogenic infrared action spectroscopy in combination with a free electron laser.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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