Electrochemical investigation of covalently post-synthetic modified SURGEL coatings-Reference-Cited by-同舟云学术

Electrochemical investigation of covalently post-synthetic modified SURGEL coatings

Published:2014 Issue:76 Volume:50 Page:11129-11131
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Mugnaini V.¹²³,Tsotsalas M.¹²³,Bebensee F.¹²³,Grosjean S.⁴⁵⁶⁷⁵,Shahnas A.¹²³,Bräse S.⁴⁵⁶⁷⁵,Lahann J.¹²³,Buck M.⁸⁹¹⁰,Wöll C.¹²³

Affiliation:

1. Institute of Functional Interfaces (IFG)

2. Karlsruhe Institute of Technology

3. Eggenstein-Leopoldshafen, Germany

4. Institute for Organic Chemistry (IOC)

5. Karlsruhe Institute of Technology (KIT)

6. 76131 Karlsruhe, Germany

7. Institute of Toxicology and Genetics (ITG)

8. EaStCHEM School of Chemistry

9. University of St Andrews

10. , UK

Abstract

Thiol–yne click chemistry post synthesis modification (PSM) is used to further functionalize a fully organic porous polymer coating (SURGEL). By cyclic voltammetry the resulting electrochemical properties are addressed. The Nernstian diffusion limited process observed in the presence of ferrocene as electrolyte is explained in terms of a high permeability of the SURGELs for ferrocene after PSM.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC03521F

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