The influence of different cations on the structure and spectral properties of Ln3+ tetrakis-complexes with the CAPh-type ligand dimethyl-N-trichloroacetylamidophosphate

Author:

Struhatska Mariia B.1,Kariaka Nataliia S.1ORCID,Dyakonenko Viktoriya V.2,Shishkina Svitlana V.2ORCID,Smola Sergii S.3,Rusakova Nataliia V.3,Gawryszewska Paula4,Malta Oscar L.5,Carneiro Neto Albano N.6ORCID,Trush Viktor O.1ORCID,Amirkhanov Volodymyr M.1ORCID

Affiliation:

1. Inorganic Chemistry Department, Taras Shevchenko National University of Kyiv, 12, Lva Tolstogo str., Kyiv 01601, Ukraine

2. SSI “Institute for Single Crystals”, National Academy of Sciences of Ukraine, Nauky ave. 60, Kharkiv 61001, Ukraine

3. A.V. Bogatsky Physicochemical Institute, NAS of Ukraine, 86, Lustdorfska doroga str., Odessa 65080, Ukraine

4. Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie Str., 50-383, Wroclaw, Poland

5. Departamento de Química Fundamental, Universidade Federal de Pernambuco, 50740-560, Recife, Brazil

6. Physics Department and CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193, Aveiro, Portugal

Abstract

The influence of the cation on the structure and properties of carbacylamidophosphate based tetrakis-complexes of lanthanides was studied. Density functional theory was applied for more detailed analysis of the complexes’ luminescence.

Funder

Ministry of Education and Science of Ukraine

Centro de Investigação em Materiais Cerâmicos e Compósitos

Publisher

Royal Society of Chemistry (RSC)

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