Revisiting the iridacycle-catalyzed hydrosilylation of enolizable imines

Author:

Pèrez-Miqueo Jorge12345,San Nacianceno Virginia12345ORCID,Urquiola F. Borja12345ORCID,Freixa Zoraida12345ORCID

Affiliation:

1. Department of Applied Chemistry

2. Faculty of Chemistry

3. University of the Basque Country (UPV-EHU)

4. San Sebastián

5. Spain

Abstract

In situ1H NMR spectroscopy reveals a cascade mechanism for the hydrosilylation of enolizable imines catalyzed by iridium(iii) metallacycles.

Funder

Ikerbasque, Basque Foundation for Science

Ministerio de Economía y Competitividad

Euskal Herriko Unibertsitatea

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. State of the Art in Rhodium- and Iridium-Catalyzed Hydrosilylation Reactions;Perspectives of Hydrosilylation Reactions;2023

2. Half-Sandwich Rhodium and Iridium Complexes;Comprehensive Organometallic Chemistry IV;2022

3. Implication of a Silyl Cobalt Dihydride Complex as a Useful Catalyst for the Hydrosilylation of Imines;ACS Catalysis;2021-11-10

4. Iridium-Catalyzed Silylation;Iridium Catalysts for Organic Reactions;2020

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