Pd–In intermetallic nanoparticles with high catalytic selectivity for liquid-phase semi-hydrogenation of diphenylacetylene-Reference-Cited by-同舟云学术

Pd–In intermetallic nanoparticles with high catalytic selectivity for liquid-phase semi-hydrogenation of diphenylacetylene

Published:2022 Issue:47 Volume:14 Page:17661-17669
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Chen Si¹,Huang Xiaohui²³,Schild Dieter⁴^ORCID,Wang Di²⁵,Kübel Christian²³⁵^ORCID,Behrens Silke¹^ORCID

Affiliation:

1. Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

2. Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

3. Joint Research Laboratory Nanomaterials, Technische Universität Darmstadt, Jovanka-Bontschits-Straße 2, 64287, Darmstadt, Germany

4. Institute for Nuclear Waste Disposal (INE), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

5. Karlsruhe Nano Micro Facility, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany

Abstract

Intermetallic Pd3In, PdIn and Pd3In7 nanoparticles are synthesized in ionic liquids and employed as catalysts in the semi-hydrogenation of diphenylacetylene. PdIn nanoparticles reveal high activity and selectivity to cis-stilbene at full conversion.

Funder

China Scholarship Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NR/D2NR03674F

Reference69 articles.

1. Advances in the Design of Nanostructured Catalysts for Selective Hydrogenation

2. Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms