Mechanism and free energy profile of base-catalyzed Knoevenagel condensation reaction-Reference-Cited by-同舟云学术

Mechanism and free energy profile of base-catalyzed Knoevenagel condensation reaction

Published:2016 Issue:63 Volume:6 Page:57803-57810
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Dalessandro Ellen V.¹²³⁴,Collin Hugo P.¹²³⁴,Valle Marcelo S.¹²³⁴,Pliego Josefredo R.¹²³⁴

Affiliation:

1. Departamento de Ciências Naturais

2. Universidade Federal de São João del-Rei

3. São João del-Rei

4. Brazil

Abstract

A reliable theoretical calculation of the free energy profile of a base-catalyzed Knoevenagel reaction shows that hydroxide ion elimination step is rate determining.

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA10393F

Reference54 articles.

1. Iminium Catalysis

2. Synthetic and theoretical study on proline-catalyzed Knoevenagel condensation in ionic liquid

3. Emil Knoevenagel and the Roots of Aminocatalysis

4. First report of the application of simple molecular complexes as organo-catalysts for Knoevenagel condensation

5. A mini-review on solid superbase catalysts developed in the past two decades

Cited by 26 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Photo-Activated Carbon Dots as Catalysts in Knoevenagel Condensation: An Advance in the Synthetic Field;Photochem;2024-08-27

2. Organocatalytic Synthesis of (Hetero)arylidene Malononitriles Using a More Sustainable, Greener, and Scalable Strategy;Current Organic Synthesis;2024-08

3. Self-assembly of s-indacene-tetrone on Cu(111): molecular trapping and patterning of Cu adatoms;Physical Chemistry Chemical Physics;2023

4. Spontaneous Enantiomeric Resolution of 1,3-Diols from the Naphtylidene Derivative of 2,4-Pentanedione;Molbank;2022-09-30

5. Near‐Infrared Fluorophores Based on Heptamethine Cyanine Dyes: From Their Synthesis and Photophysical Properties to Recent Optical Sensing and Bioimaging Applications;Asian Journal of Organic Chemistry;2022-04-26